Hydrometallurgy Process for Lithium-Ion Recycling & the Importance of Filtration

Filtration Solutions for Li-Ion Battery Recycling to Help You Achieve Maximum Metal Recovery

Need of Recycling Lithium-Ion-Batteries (LIB)

 

As the world transitions towards a greener future, the demand for electric vehicles (EVs) continues to soar. With this surge in popularity, the need for efficient and sustainable recycling methods for Lithium-Ion-Batteries (LIBs) has become increasingly important. One such method gaining traction in the lithium recycling industry is hydrometallurgy, which utilizes chemical processes to extract valuable metals from used LIBs.

 

Different Methods to Recycle LIBs

 

New recycling technologies have emerged in recent years, revolutionizing the electric vehicle (EV) battery recycling landscape. These innovative techniques focus on maximizing resource recovery, reducing waste, and minimizing the environmental impact of battery disposal.

Pyrometallurgy

Involves high-temperature smelting to extract metals; it is energy-intensive with significant greenhouse gas emissions.

Hydrometallurgy

Uses aqueous chemistry to leach metals, offering higher recovery rates, lower energy consumption, and minimal environmental impact.

Direct Recycling

A method that recovers and refurbishes battery components without entirely breaking them down, is a testament to the depth of technical expertise required in this field. It is a technically complex process that demands high skill and knowledge.

Filtration solution for Hydrometallurgy Process for Recycling LIB

 

Hydrometallurgy is the preferred method for recycling lithium-ion batteries due to its higher recovery rates, lower energy consumption, reduced greenhouse gas emissions, and minimal air pollutants compared to pyrometallurgy. Its aqueous processes enable selective extraction and purification of metals, making it an environmentally friendly and efficient option that aligns with both economic and ecological goals.

 

The hydrometallurgy process for recycling LIBs involves several crucial steps, with filtration playing a vital role in ensuring the efficiency and quality of the overall process. Let's explore the significance of the process and the filtration solutions in more detail.

Hydrometallurgy Process for Recycling Lithium-Ion-Batteries showing options for Chemical Precipitation, solvent Extraction and selective Metal Adsorption Beds

 

Process LocationSeparation ValueSeparation Product
ASeparate graphite from dissolved metalsAutomated Regenerative Cartridge
BRecover Metal and Lithium productsAutomated Regenerative Cartridge
CSeparate Acid Solution from Organic Solvent with MetalsLiquid-Liquid Coalescer Cartridge
DProtect metal Adsorbent Beds from Fouling10 Micron Filter

 

Steps in Hydrometallurgy Process of Lithium-Ion Battery Recycling

 

1Shredding and SeparationThe first step in the recycling process is to shred the LIBs and mechanically separate the black mass, which contains valuable metals, from other components, such as the casing, separator membrane, and metal foil electrodes.
2Metal ExtractionOnce the black mass is isolated, it undergoes an extraction process using sulfuric acid. The acid dissolves the valuable metals in LIBs, including Cobalt, Nickel, Manganese, and Lithium. However, removing any insoluble graphite materials and other contaminants from the acid solution is crucial during this section, which is where filtration comes into play.
3FiltrationFiltration is an essential step in lithium-ion recycling using hydrometallurgy. It helps separate the insoluble graphite materials from the acid solution containing the dissolved metals. Solid particles are effectively removed after passing the acid solution through a filtration system, allowing for a clean and clarified solution to proceed to the next stage. Filtration improves the solution’s purity and prevents any potential blockages in downstream processes.
4Metal Recovery

After the filtration step, the acid solution, which now contains dissolved metals, is subjected to further treatment to recover the metals for reuse. Several methods that can be employed, such as chemical precipitation, solvent extraction, or adsorbent beds.

 

  • Chemical Precipitation: In this method, the pH of the acid solution is adjusted using caustic to precipitate different metals selectively. The precipitates are then collected using a reliable filtration system to separate them effectively.
  • Solvent Extraction: Solvent extraction involves using an organic solvent containing an ion-specific chelating agent to remove the metals from the aqueous solution. Filtration is crucial in this process to prevent emulsion carryover and to recover the valuable solvent. Filtration systems, such as liquid-liquid coalescers, are employed downstream of the extractor to ensure efficient separation.
  • Adsorbent Beds: This method uses granular solids or resin beads with specialized chemistry to selectively remove specific metals from the aqueous feed stream. Filtration is necessary to protect the adsorbent beds from fouling caused by solid contaminants in the incoming stream. After separating the metals onto the adsorbent beds, they are eluted using an acid solution in a separate step.
5Concentration and CrystallizationFollowing the metal recovery step, further concentration and crystallization processes may be employed to obtain higher-purity final products. Although not depicted in the simplified figure, these additional steps are crucial to ensuring the quality and market value of the recovered metals.

 

Improve Efficiency of LIB Recycler with Pall’s Filtration Solutions

Filtration plays a pivotal role in lithium-ion recycling using hydrometallurgy. It not only removes solid particles and contaminants from the acid solution but also ensures the smooth operation of downstream processes. Effective filtration helps maintain the purity of the recovered metals, enhances process efficiency, and minimizes the risk of equipment damage or blockages.

 

By incorporating efficient filtration systems into the hydrometallurgy process for LIB recycling, we can achieve sustainable and responsible battery disposal while maximizing the recovery of valuable metals. By reducing the need for raw material extraction, we can promote a greener future and contribute to the development of a circular economy.

 

At Pall Corporation, we recognize the significance of filtration in lithium-ion recycling and offer state-of-the-art filtration solutions tailored to the specific requirements of the battery recycling industry. Our advanced filtration technologies ensure optimal separation efficiency, minimal downtime, and reduced environmental impact. Contact us today to discover how our filtration solutions can enhance your battery recycling processes and contribute to a more sustainable tomorrow.

 

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